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Proceso de polimerizacion de monomeros polares empleando catalizadores de titanio.

La presente invencin se refiere a un mtodo nuevo para la sntesis de polmeros de polialquil vinil teres (pve), polisilil vinil teres (psive) y poli vinilcarbazol (pvk), a travs de la (ver mas)
La presente invencin se refiere a un mtodo nuevo para la sntesis de polmeros de polialquil vinil teres (pve), polisilil vinil teres (psive) y poli vinilcarbazol (pvk), a travs de la polimerizacin de monmeros polares empleando el sistema cataltico formado por un catalizador homogneo medio de sndwich de titanio con frmula general ltix3 , [ l= c5h5, c5me5, c9h7; x= halgeno, alquilo, alcoxi] y un cocatalizador alquilaluminoxano.Las caractersticas estructurales de los polmeros que se obtienen por el mtodo de la presente invencin son diferentes a las obtenidas por otros mtodos de polimerizacin convencionales. El mtodo conduce a polmeros estereoregulares enriquecidos de arreglos sindiotcticos isotcticos y heteroatcticos. En particular se destaca la obtencin de poli (terbutil vinil ter) heteroatctico, cuya hidrlisis total o parcial conduce a pva con estructura diferentes al pva comercial. Los pesos moleculares de los polmeros pve, psive y pvk son comparables a los ms altos que se han reportado en la literatura.

Palabras clave: psive y pvk; polisilil vinil; presente invenci; meros; vinil;

Nombre del Agente: JOS ANTONIO ROMERO MIRANDA; Thiers 251, Piso 14, Anzures, 11590, , Distrito Federal

Titular: CENTRO DE INVESTIGACION EN QUIMICA APLICADA

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